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Uranium concentrations and isotope ratios Bahamas seawater and ODP holes pore-water

The geometry, timing, and rate of fluid-flow through carbonate margins and platforms is not well constrained. In this study, we use U concentrations and isotope ratios measured on small volumes of pore-water from Bahamas slope sediment, coupled with existing chlorinity data, to place constraints on the fluid-flow in this region and, by implication, other carbonate platforms. These data also allow an assessment of the behaviour of U isotopes in an unusually well constrained water-rock system. We report pore-water U concentrations which are controlled by dissolution of high-U organic material at shallow depths in the sediment and by reduction of U to its insoluble 4+ state at greater depths. The dominant process influencing pore-water (234U/238U) is alpha recoil. In Holocene sediments, the increase of pore-water (234U/238U) due to recoil provides an estimate of the horizontal flow rate of 11 cm/year, but with considerable uncertainty. At depths in the sediment where conditions are reducing, features in the U concentration and (234U/238U) profiles are offset from one another which constrains the effective diffusivity for U in these sediments to be c. 1-2 * 10-8 cm2/s. At depths between the Holocene and these reducing sediments, pore-water (234U/238U) values are unusually low due to a recent increase in the dissolution rate of grain surfaces. This suggests a strengthening of fluid flow, probably due to the flooding of the banks at the last deglaciation and the re-initiation of thermally-driven venting of fluid on the bank top and accompanying recharge on the slopes. Interpretation of existing chlorinity data, in the light of this change in flow rate, constrain the recent horizontal flow rate to be 10.6 ( 3.4) cm/year. Estimates of flow rate from (234U/238U) and Cl[-] are therefore in agreement and suggest flow rates close to those predicted by thermally-driven models of fluid flow. This agreement supports the idea that flow within the Bahamas Banks is mostly thermally driven and suggests that flow rates on the order of 10 cm/year are typical for carbonate platforms where such flow occurs.

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Henderson, Gideon M, Slowey, Niall C, Haddad, Geoffrey A (1999). Dataset: Uranium concentrations and isotope ratios Bahamas seawater and ODP holes pore-water. https://doi.org/10.1594/PANGAEA.711398

DOI retrieved: 1999

Additional Info

Field Value
Imported on November 29, 2024
Last update November 29, 2024
License CC-BY-3.0
Source https://doi.org/10.1594/PANGAEA.711398
Author Henderson, Gideon M
Given Name Gideon M
Family Name Henderson
More Authors
Slowey, Niall C
Haddad, Geoffrey A
Source Creation 1999
Publication Year 1999
Resource Type application/zip - filename: Henderson_1999
Subject Areas
Name: Geophysics

Related Identifiers
Title: Fluid flow through carbonate platforms: constraints from 234U/238U and Cl[-] in Bahamas pore-waters
Identifier: https://doi.org/10.1016/S0012-821X(99)00065-5
Type: DOI
Relation: IsSupplementTo
Year: 1999
Source: Earth and Planetary Science Letters
Authors: Henderson Gideon M , Slowey Niall C , Haddad Geoffrey A .