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f | 1 | { | f | 1 | { |
2 | "author": "Huang, Xiaohui", | 2 | "author": "Huang, Xiaohui", | ||
3 | "author_email": "", | 3 | "author_email": "", | ||
4 | "creator_user_id": "17755db4-395a-4b3b-ac09-e8e3484ca700", | 4 | "creator_user_id": "17755db4-395a-4b3b-ac09-e8e3484ca700", | ||
5 | "doi": "10.35097/1414", | 5 | "doi": "10.35097/1414", | ||
6 | "doi_date_published": "2023", | 6 | "doi_date_published": "2023", | ||
7 | "doi_publisher": "", | 7 | "doi_publisher": "", | ||
8 | "doi_status": "True", | 8 | "doi_status": "True", | ||
9 | "extra_authors": [ | 9 | "extra_authors": [ | ||
10 | { | 10 | { | ||
11 | "extra_author": "Barlocco, Ilaria", | 11 | "extra_author": "Barlocco, Ilaria", | ||
12 | "orcid": "" | 12 | "orcid": "" | ||
13 | }, | 13 | }, | ||
14 | { | 14 | { | ||
15 | "extra_author": "Villa, Alberto", | 15 | "extra_author": "Villa, Alberto", | ||
16 | "orcid": "" | 16 | "orcid": "" | ||
17 | }, | 17 | }, | ||
18 | { | 18 | { | ||
19 | "extra_author": "K\u00fcbel, Christian", | 19 | "extra_author": "K\u00fcbel, Christian", | ||
20 | "orcid": "0000-0001-5701-4006" | 20 | "orcid": "0000-0001-5701-4006" | ||
21 | }, | 21 | }, | ||
22 | { | 22 | { | ||
23 | "extra_author": "Wang, Di", | 23 | "extra_author": "Wang, Di", | ||
24 | "orcid": "0000-0001-9817-7047" | 24 | "orcid": "0000-0001-9817-7047" | ||
25 | } | 25 | } | ||
26 | ], | 26 | ], | ||
27 | "groups": [], | 27 | "groups": [], | ||
28 | "id": "5dd2550a-c8e2-4968-97bd-5570d69a4b3d", | 28 | "id": "5dd2550a-c8e2-4968-97bd-5570d69a4b3d", | ||
29 | "isopen": false, | 29 | "isopen": false, | ||
30 | "license_id": "CC BY-NC 4.0 Attribution-NonCommercial", | 30 | "license_id": "CC BY-NC 4.0 Attribution-NonCommercial", | ||
31 | "license_title": "CC BY-NC 4.0 Attribution-NonCommercial", | 31 | "license_title": "CC BY-NC 4.0 Attribution-NonCommercial", | ||
32 | "metadata_created": "2023-08-04T08:50:44.747483", | 32 | "metadata_created": "2023-08-04T08:50:44.747483", | ||
t | 33 | "metadata_modified": "2023-08-04T08:53:35.469365", | t | 33 | "metadata_modified": "2023-08-04T09:04:17.092387", |
34 | "name": "rdr-doi-10-35097-1414", | 34 | "name": "rdr-doi-10-35097-1414", | ||
35 | "notes": "Abstract: Supported nanocatalysts exhibit different | 35 | "notes": "Abstract: Supported nanocatalysts exhibit different | ||
36 | performance in batch and fixed bed reactors for a wide range of liquid | 36 | performance in batch and fixed bed reactors for a wide range of liquid | ||
37 | phase catalytic reactions due to differences in metal leaching. To | 37 | phase catalytic reactions due to differences in metal leaching. To | ||
38 | investigate this leaching process and its influence on the catalytic | 38 | investigate this leaching process and its influence on the catalytic | ||
39 | performance, a quantitative 3D characterization of the particle size | 39 | performance, a quantitative 3D characterization of the particle size | ||
40 | and the particle distribution is important to follow the structural | 40 | and the particle distribution is important to follow the structural | ||
41 | evolution of the active metal catalysts supported on porous materials | 41 | evolution of the active metal catalysts supported on porous materials | ||
42 | during the reaction. In this work, electron tomography has been | 42 | during the reaction. In this work, electron tomography has been | ||
43 | applied to uncover leaching and redeposition of a Pd@CMK3 catalyst | 43 | applied to uncover leaching and redeposition of a Pd@CMK3 catalyst | ||
44 | during formic acid decomposition in batch and fixed bed reactors. The | 44 | during formic acid decomposition in batch and fixed bed reactors. The | ||
45 | 3D distribution of Pd NPs on the mesoporous carbon CMK3 has been | 45 | 3D distribution of Pd NPs on the mesoporous carbon CMK3 has been | ||
46 | determined by a quantitative tomographic analysis and the determined | 46 | determined by a quantitative tomographic analysis and the determined | ||
47 | structural changes are correlated with the observed differences in | 47 | structural changes are correlated with the observed differences in | ||
48 | activity and stability of formic acid decomposition using batch and | 48 | activity and stability of formic acid decomposition using batch and | ||
49 | fixed bed reactors.\r\nTechnicalRemarks: Descriptions of the data | 49 | fixed bed reactors.\r\nTechnicalRemarks: Descriptions of the data | ||
50 | formats are provided in the subdirectory 'description'", | 50 | formats are provided in the subdirectory 'description'", | ||
51 | "num_resources": 0, | 51 | "num_resources": 0, | ||
52 | "num_tags": 5, | 52 | "num_tags": 5, | ||
53 | "orcid": "", | 53 | "orcid": "", | ||
54 | "organization": { | 54 | "organization": { | ||
55 | "approval_status": "approved", | 55 | "approval_status": "approved", | ||
56 | "created": "2023-01-12T13:30:23.238233", | 56 | "created": "2023-01-12T13:30:23.238233", | ||
57 | "description": "RADAR (Research Data Repository) is a | 57 | "description": "RADAR (Research Data Repository) is a | ||
58 | cross-disciplinary repository for archiving and publishing research | 58 | cross-disciplinary repository for archiving and publishing research | ||
59 | data from completed scientific studies and projects. The focus is on | 59 | data from completed scientific studies and projects. The focus is on | ||
60 | research data from subjects that do not yet have their own | 60 | research data from subjects that do not yet have their own | ||
61 | discipline-specific infrastructures for research data management. ", | 61 | discipline-specific infrastructures for research data management. ", | ||
62 | "id": "013c89a9-383c-4200-8baa-0f78bf1d91f9", | 62 | "id": "013c89a9-383c-4200-8baa-0f78bf1d91f9", | ||
63 | "image_url": "radar-logo.svg", | 63 | "image_url": "radar-logo.svg", | ||
64 | "is_organization": true, | 64 | "is_organization": true, | ||
65 | "name": "radar", | 65 | "name": "radar", | ||
66 | "state": "active", | 66 | "state": "active", | ||
67 | "title": "RADAR", | 67 | "title": "RADAR", | ||
68 | "type": "organization" | 68 | "type": "organization" | ||
69 | }, | 69 | }, | ||
70 | "owner_org": "013c89a9-383c-4200-8baa-0f78bf1d91f9", | 70 | "owner_org": "013c89a9-383c-4200-8baa-0f78bf1d91f9", | ||
71 | "private": false, | 71 | "private": false, | ||
72 | "production_year": "2023", | 72 | "production_year": "2023", | ||
73 | "publication_year": "2023", | 73 | "publication_year": "2023", | ||
74 | "publishers": [ | 74 | "publishers": [ | ||
75 | { | 75 | { | ||
76 | "publisher": "Karlsruhe Institute of Technology" | 76 | "publisher": "Karlsruhe Institute of Technology" | ||
77 | } | 77 | } | ||
78 | ], | 78 | ], | ||
79 | "relationships_as_object": [], | 79 | "relationships_as_object": [], | ||
80 | "relationships_as_subject": [], | 80 | "relationships_as_subject": [], | ||
81 | "repository_name": "RADAR (Research Data Repository)", | 81 | "repository_name": "RADAR (Research Data Repository)", | ||
82 | "resources": [], | 82 | "resources": [], | ||
83 | "services_used_list": "", | 83 | "services_used_list": "", | ||
84 | "source_metadata_created": "2023", | 84 | "source_metadata_created": "2023", | ||
85 | "source_metadata_modified": "", | 85 | "source_metadata_modified": "", | ||
86 | "state": "active", | 86 | "state": "active", | ||
87 | "subject_areas": [ | 87 | "subject_areas": [ | ||
88 | { | 88 | { | ||
89 | "subject_area_additional": "", | 89 | "subject_area_additional": "", | ||
90 | "subject_area_name": "Engineering" | 90 | "subject_area_name": "Engineering" | ||
91 | } | 91 | } | ||
92 | ], | 92 | ], | ||
93 | "tags": [ | 93 | "tags": [ | ||
94 | { | 94 | { | ||
95 | "display_name": "Batch reactor", | 95 | "display_name": "Batch reactor", | ||
96 | "id": "ba1ed147-0efd-4a64-b9d3-a4d024ff6c22", | 96 | "id": "ba1ed147-0efd-4a64-b9d3-a4d024ff6c22", | ||
97 | "name": "Batch reactor", | 97 | "name": "Batch reactor", | ||
98 | "state": "active", | 98 | "state": "active", | ||
99 | "vocabulary_id": null | 99 | "vocabulary_id": null | ||
100 | }, | 100 | }, | ||
101 | { | 101 | { | ||
102 | "display_name": "Electron tomography", | 102 | "display_name": "Electron tomography", | ||
103 | "id": "ee1d0138-0ced-4832-b570-e8e154a11f22", | 103 | "id": "ee1d0138-0ced-4832-b570-e8e154a11f22", | ||
104 | "name": "Electron tomography", | 104 | "name": "Electron tomography", | ||
105 | "state": "active", | 105 | "state": "active", | ||
106 | "vocabulary_id": null | 106 | "vocabulary_id": null | ||
107 | }, | 107 | }, | ||
108 | { | 108 | { | ||
109 | "display_name": "Fixed bed reactor", | 109 | "display_name": "Fixed bed reactor", | ||
110 | "id": "956aa454-d716-4f8d-b5b8-7504eacafc7a", | 110 | "id": "956aa454-d716-4f8d-b5b8-7504eacafc7a", | ||
111 | "name": "Fixed bed reactor", | 111 | "name": "Fixed bed reactor", | ||
112 | "state": "active", | 112 | "state": "active", | ||
113 | "vocabulary_id": null | 113 | "vocabulary_id": null | ||
114 | }, | 114 | }, | ||
115 | { | 115 | { | ||
116 | "display_name": "Formic acid decomposition", | 116 | "display_name": "Formic acid decomposition", | ||
117 | "id": "c5c5cb75-aaf7-4285-af40-37c63f5928cb", | 117 | "id": "c5c5cb75-aaf7-4285-af40-37c63f5928cb", | ||
118 | "name": "Formic acid decomposition", | 118 | "name": "Formic acid decomposition", | ||
119 | "state": "active", | 119 | "state": "active", | ||
120 | "vocabulary_id": null | 120 | "vocabulary_id": null | ||
121 | }, | 121 | }, | ||
122 | { | 122 | { | ||
123 | "display_name": "Leaching and Redeposition", | 123 | "display_name": "Leaching and Redeposition", | ||
124 | "id": "e7cf4d9e-3f51-4723-8f7a-6f27d96335a9", | 124 | "id": "e7cf4d9e-3f51-4723-8f7a-6f27d96335a9", | ||
125 | "name": "Leaching and Redeposition", | 125 | "name": "Leaching and Redeposition", | ||
126 | "state": "active", | 126 | "state": "active", | ||
127 | "vocabulary_id": null | 127 | "vocabulary_id": null | ||
128 | } | 128 | } | ||
129 | ], | 129 | ], | ||
130 | "title": "Disclosing the leaching behaviour of pd@cmk3 catalysts in | 130 | "title": "Disclosing the leaching behaviour of pd@cmk3 catalysts in | ||
131 | formic acid decomposition by electron tomography", | 131 | formic acid decomposition by electron tomography", | ||
132 | "type": "vdataset", | 132 | "type": "vdataset", | ||
133 | "url": "https://doi.org/10.35097/1414" | 133 | "url": "https://doi.org/10.35097/1414" | ||
134 | } | 134 | } |