Changes

              
    

          
          
        
        

            
f
1
{
f
1
{
            
2
  "author": "Huang, Xiaohui",
2
  "author": "Huang, Xiaohui",
            
3
  "author_email": "",
3
  "author_email": "",
            
n
n
4
  "citation": [],
            
4
  "creator_user_id": "17755db4-395a-4b3b-ac09-e8e3484ca700",
5
  "creator_user_id": "17755db4-395a-4b3b-ac09-e8e3484ca700",
            
5
  "doi": "10.35097/1414",
6
  "doi": "10.35097/1414",
            
6
  "doi_date_published": "2023",
7
  "doi_date_published": "2023",
            
7
  "doi_publisher": "",
8
  "doi_publisher": "",
            
8
  "doi_status": "True",
9
  "doi_status": "True",
            
9
  "extra_authors": [
10
  "extra_authors": [
            
10
    {
11
    {
            
11
      "extra_author": "Barlocco, Ilaria",
12
      "extra_author": "Barlocco, Ilaria",
            
n
n
13
      "familyName": "Barlocco",
            
14
      "givenName": "Ilaria",
            
12
      "orcid": ""
15
      "orcid": ""
            
13
    },
16
    },
            
14
    {
17
    {
            
15
      "extra_author": "Villa, Alberto",
18
      "extra_author": "Villa, Alberto",
            
n
n
19
      "familyName": "Villa",
            
20
      "givenName": "Alberto",
            
16
      "orcid": ""
21
      "orcid": ""
            
17
    },
22
    },
            
18
    {
23
    {
            
19
      "extra_author": "K\u00fcbel, Christian",
24
      "extra_author": "K\u00fcbel, Christian",
            
n
n
25
      "familyName": "K\u00fcbel",
            
26
      "givenName": "Christian",
            
20
      "orcid": "0000-0001-5701-4006"
27
      "orcid": "0000-0001-5701-4006"
            
21
    },
28
    },
            
22
    {
29
    {
            
23
      "extra_author": "Wang, Di",
30
      "extra_author": "Wang, Di",
            
n
n
31
      "familyName": "Wang",
            
32
      "givenName": "Di",
            
24
      "orcid": "0000-0001-9817-7047"
33
      "orcid": "0000-0001-9817-7047"
            
25
    }
34
    }
            
26
  ],
35
  ],
            
n
n
36
  "familyName": "Huang",
            
37
  "givenName": "Xiaohui",
            
27
  "groups": [],
38
  "groups": [],
            
28
  "id": "5dd2550a-c8e2-4968-97bd-5570d69a4b3d",
39
  "id": "5dd2550a-c8e2-4968-97bd-5570d69a4b3d",
            
29
  "isopen": false,
40
  "isopen": false,
            
30
  "license_id": "CC BY-NC 4.0 Attribution-NonCommercial",
41
  "license_id": "CC BY-NC 4.0 Attribution-NonCommercial",
            
31
  "license_title": "CC BY-NC 4.0 Attribution-NonCommercial",
42
  "license_title": "CC BY-NC 4.0 Attribution-NonCommercial",
            
32
  "metadata_created": "2023-08-04T08:50:44.747483",
43
  "metadata_created": "2023-08-04T08:50:44.747483",
            
t
33
  "metadata_modified": "2023-08-04T09:31:21.952510",
t
44
  "metadata_modified": "2024-11-28T13:15:34.683119",
            
34
  "name": "rdr-doi-10-35097-1414",
45
  "name": "rdr-doi-10-35097-1414",
            
35
  "notes": "Abstract: Supported nanocatalysts exhibit different 
46
  "notes": "Abstract: Supported nanocatalysts exhibit different 
            
36
performance in batch and fixed bed reactors for a wide range of liquid 
47
performance in batch and fixed bed reactors for a wide range of liquid 
            
37
phase catalytic reactions due to differences in metal leaching. To 
48
phase catalytic reactions due to differences in metal leaching. To 
            
38
investigate this leaching process and its influence on the catalytic 
49
investigate this leaching process and its influence on the catalytic 
            
39
performance, a quantitative 3D characterization of the particle size 
50
performance, a quantitative 3D characterization of the particle size 
            
40
and the particle distribution is important to follow the structural 
51
and the particle distribution is important to follow the structural 
            
41
evolution of the active metal catalysts supported on porous materials 
52
evolution of the active metal catalysts supported on porous materials 
            
42
during the reaction. In this work, electron tomography has been 
53
during the reaction. In this work, electron tomography has been 
            
43
applied to uncover leaching and redeposition of a Pd@CMK3 catalyst 
54
applied to uncover leaching and redeposition of a Pd@CMK3 catalyst 
            
44
during formic acid decomposition in batch and fixed bed reactors. The 
55
during formic acid decomposition in batch and fixed bed reactors. The 
            
45
3D distribution of Pd NPs on the mesoporous carbon CMK3 has been 
56
3D distribution of Pd NPs on the mesoporous carbon CMK3 has been 
            
46
determined by a quantitative tomographic analysis and the determined 
57
determined by a quantitative tomographic analysis and the determined 
            
47
structural changes are correlated with the observed differences in 
58
structural changes are correlated with the observed differences in 
            
48
activity and stability of formic acid decomposition using batch and 
59
activity and stability of formic acid decomposition using batch and 
            
49
fixed bed reactors.\r\nTechnicalRemarks: Descriptions of the data 
60
fixed bed reactors.\r\nTechnicalRemarks: Descriptions of the data 
            
50
formats are provided in the subdirectory 'description'",
61
formats are provided in the subdirectory 'description'",
            
51
  "num_resources": 0,
62
  "num_resources": 0,
            
52
  "num_tags": 5,
63
  "num_tags": 5,
            
53
  "orcid": "",
64
  "orcid": "",
            
54
  "organization": {
65
  "organization": {
            
55
    "approval_status": "approved",
66
    "approval_status": "approved",
            
56
    "created": "2023-01-12T13:30:23.238233",
67
    "created": "2023-01-12T13:30:23.238233",
            
57
    "description": "RADAR (Research Data Repository) is a 
68
    "description": "RADAR (Research Data Repository) is a 
            
58
cross-disciplinary repository for archiving and publishing research 
69
cross-disciplinary repository for archiving and publishing research 
            
59
data from completed scientific studies and projects. The focus is on 
70
data from completed scientific studies and projects. The focus is on 
            
60
research data from subjects that do not yet have their own 
71
research data from subjects that do not yet have their own 
            
61
discipline-specific infrastructures for research data management. ",
72
discipline-specific infrastructures for research data management. ",
            
62
    "id": "013c89a9-383c-4200-8baa-0f78bf1d91f9",
73
    "id": "013c89a9-383c-4200-8baa-0f78bf1d91f9",
            
63
    "image_url": "radar-logo.svg",
74
    "image_url": "radar-logo.svg",
            
64
    "is_organization": true,
75
    "is_organization": true,
            
65
    "name": "radar",
76
    "name": "radar",
            
66
    "state": "active",
77
    "state": "active",
            
67
    "title": "RADAR",
78
    "title": "RADAR",
            
68
    "type": "organization"
79
    "type": "organization"
            
69
  },
80
  },
            
70
  "owner_org": "013c89a9-383c-4200-8baa-0f78bf1d91f9",
81
  "owner_org": "013c89a9-383c-4200-8baa-0f78bf1d91f9",
            
71
  "private": false,
82
  "private": false,
            
72
  "production_year": "2023",
83
  "production_year": "2023",
            
73
  "publication_year": "2023",
84
  "publication_year": "2023",
            
74
  "publishers": [
85
  "publishers": [
            
75
    {
86
    {
            
76
      "publisher": "Karlsruhe Institute of Technology"
87
      "publisher": "Karlsruhe Institute of Technology"
            
77
    }
88
    }
            
78
  ],
89
  ],
            
79
  "relationships_as_object": [],
90
  "relationships_as_object": [],
            
80
  "relationships_as_subject": [],
91
  "relationships_as_subject": [],
            
81
  "repository_name": "RADAR (Research Data Repository)",
92
  "repository_name": "RADAR (Research Data Repository)",
            
82
  "resources": [],
93
  "resources": [],
            
83
  "services_used_list": "",
94
  "services_used_list": "",
            
84
  "source_metadata_created": "2023",
95
  "source_metadata_created": "2023",
            
85
  "source_metadata_modified": "",
96
  "source_metadata_modified": "",
            
86
  "state": "active",
97
  "state": "active",
            
87
  "subject_areas": [
98
  "subject_areas": [
            
88
    {
99
    {
            
89
      "subject_area_additional": "",
100
      "subject_area_additional": "",
            
90
      "subject_area_name": "Engineering"
101
      "subject_area_name": "Engineering"
            
91
    }
102
    }
            
92
  ],
103
  ],
            
93
  "tags": [
104
  "tags": [
            
94
    {
105
    {
            
95
      "display_name": "Batch reactor",
106
      "display_name": "Batch reactor",
            
96
      "id": "ba1ed147-0efd-4a64-b9d3-a4d024ff6c22",
107
      "id": "ba1ed147-0efd-4a64-b9d3-a4d024ff6c22",
            
97
      "name": "Batch reactor",
108
      "name": "Batch reactor",
            
98
      "state": "active",
109
      "state": "active",
            
99
      "vocabulary_id": null
110
      "vocabulary_id": null
            
100
    },
111
    },
            
101
    {
112
    {
            
102
      "display_name": "Electron tomography",
113
      "display_name": "Electron tomography",
            
103
      "id": "ee1d0138-0ced-4832-b570-e8e154a11f22",
114
      "id": "ee1d0138-0ced-4832-b570-e8e154a11f22",
            
104
      "name": "Electron tomography",
115
      "name": "Electron tomography",
            
105
      "state": "active",
116
      "state": "active",
            
106
      "vocabulary_id": null
117
      "vocabulary_id": null
            
107
    },
118
    },
            
108
    {
119
    {
            
109
      "display_name": "Fixed bed reactor",
120
      "display_name": "Fixed bed reactor",
            
110
      "id": "956aa454-d716-4f8d-b5b8-7504eacafc7a",
121
      "id": "956aa454-d716-4f8d-b5b8-7504eacafc7a",
            
111
      "name": "Fixed bed reactor",
122
      "name": "Fixed bed reactor",
            
112
      "state": "active",
123
      "state": "active",
            
113
      "vocabulary_id": null
124
      "vocabulary_id": null
            
114
    },
125
    },
            
115
    {
126
    {
            
116
      "display_name": "Formic acid decomposition",
127
      "display_name": "Formic acid decomposition",
            
117
      "id": "c5c5cb75-aaf7-4285-af40-37c63f5928cb",
128
      "id": "c5c5cb75-aaf7-4285-af40-37c63f5928cb",
            
118
      "name": "Formic acid decomposition",
129
      "name": "Formic acid decomposition",
            
119
      "state": "active",
130
      "state": "active",
            
120
      "vocabulary_id": null
131
      "vocabulary_id": null
            
121
    },
132
    },
            
122
    {
133
    {
            
123
      "display_name": "Leaching and Redeposition",
134
      "display_name": "Leaching and Redeposition",
            
124
      "id": "e7cf4d9e-3f51-4723-8f7a-6f27d96335a9",
135
      "id": "e7cf4d9e-3f51-4723-8f7a-6f27d96335a9",
            
125
      "name": "Leaching and Redeposition",
136
      "name": "Leaching and Redeposition",
            
126
      "state": "active",
137
      "state": "active",
            
127
      "vocabulary_id": null
138
      "vocabulary_id": null
            
128
    }
139
    }
            
129
  ],
140
  ],
            
130
  "title": "Disclosing the leaching behaviour of pd@cmk3 catalysts in 
141
  "title": "Disclosing the leaching behaviour of pd@cmk3 catalysts in 
            
131
formic acid decomposition by electron tomography",
142
formic acid decomposition by electron tomography",
            
132
  "type": "vdataset",
143
  "type": "vdataset",
            
133
  "url": "https://doi.org/10.35097/1414"
144
  "url": "https://doi.org/10.35097/1414"
            
134
}
145
}