Geochemistry of Central American Volcanic Arc basement samples

The Central American Volcanic Arc (CAVA) has been the subject of intensive research over the past few years, leading to a variety of distinct models for the origin of CAVA lavas with various source components. We present a new model for the NW Central American Volcanic Arc based on a comprehensive new geochemical data set (major and trace element and Sr-Nd-Pb-Hf-O isotope ratios) of mafic volcanic front (VF), behind the volcanic front (BVF) and back-arc (BA) lava and tephra samples from NW Nicaragua, Honduras, El Salvador and Guatemala. Additionally we present data on subducting Cocos Plate sediments (from DSDP Leg 67 Sites 495 and 499) and igneous oceanic crust (from DSDP Leg 67 Site 495), and Guatemalan (Chortis Block) granitic and metamorphic continental basement. We observe systematic variations in trace element and isotopic compositions both along and across the arc. The data require at least three different endmembers for the volcanism in NW Central America. (1) The NW Nicaragua VF lavas require an endmember with very high Ba/(La, Th) and U/Th, relatively radiogenic Sr, Nd and Hf but unradiogenic Pb and low d18O, reflecting a largely serpentinite-derived fluid/hydrous melt flux from the subducting slab into a depleted N-MORB type of mantle wedge. (2) The Guatemala VF and BVF mafic lavas require an enriched endmember with low Ba/(La, Th), U/Th, high d18O and radiogenic Sr and Pb but unradiogenic Nd and Hf isotope ratios. Correlations of Hf with both Nd and Pb isotopic compositions are not consistent with this endmember being subducted sediments. Granitic samples from the Chiquimula Plutonic Complex in Guatemala have the appropriate isotopic composition to serve as this endmember, but the large amounts of assimilation required to explain the isotope data are not consistent with the basaltic compositions of the volcanic rocks. In addition, mixing regressions on Nd vs. Hf and the Sr and O isotope plots do not go through the data. Therefore, we propose that this endmember could represent pyroxenites in the lithosphere (mantle and possibly lower crust), derived from parental magmas for the plutonic rocks. (3) The Honduras and Caribbean BA lavas define an isotopically depleted endmember (with unradiogenic Sr but radiogenic Nd, Hf and Pb isotope ratios), having OIB-like major and trace element compositions (e.g. low Ba/(La, Th) and U/Th, high La/Yb). This endmember is possibly derived from melting of young, recycled oceanic crust in the asthenosphere upwelling in the back-arc. Mixing between these three endmember types of magmas can explain the observed systematic geochemical variations along and across the NW Central American Arc.

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Heydolph, Ken, Hoernle, Kaj, Hauff, Folkmar, van den Bogaard, Paul, Portnyagin, Maxim V, Bindeman, Ilya, Garbe-Schönberg, Dieter (2012). Dataset: Geochemistry of Central American Volcanic Arc basement samples. https://doi.org/10.1594/PANGAEA.815164

DOI retrieved: 2012

Additional Info

Field Value
Imported on November 30, 2024
Last update November 30, 2024
License CC-BY-3.0
Source https://doi.org/10.1594/PANGAEA.815164
Author Heydolph, Ken
Given Name Ken
Family Name Heydolph
More Authors
Hoernle, Kaj
Hauff, Folkmar
van den Bogaard, Paul
Portnyagin, Maxim V
Bindeman, Ilya
Garbe-Schönberg, Dieter
Source Creation 2012
Publication Year 2012
Resource Type application/zip - filename: Heydolph_2012
Subject Areas
Name: Chemistry

Name: Lithosphere

Related Identifiers
Title: Along and across arc geochemical variations in NW Central America: Evidence for involvement of lithospheric pyroxenite
Identifier: https://doi.org/10.1016/j.gca.2012.01.035
Type: DOI
Relation: IsSupplementTo
Year: 2012
Source: Geochimica et Cosmochimica Acta
Authors: Heydolph Ken , Hoernle Kaj , Hauff Folkmar , van den Bogaard Paul , Portnyagin Maxim V , Bindeman Ilya , Garbe-Schönberg Dieter .