Age and chemical composition of apatites from five DSDP and ODP Sites in the Pacific, Atlantic and Indian Oceans

Since studies on deep-sea cores were carried out in the early 1990s it has been known that ambient temperature may have a marked affect on apatite fission track annealing. Due to sluggish annealing kinetics, this effect cannot be quantified by laboratory annealing experiments. The unknown amount of low-temperature annealing remains one of the main uncertainties for extracting thermal histories from fission track data, particularly for samples which experienced slow cooling in shallow crustal levels. To further elucidate these uncertainties, we studied volcanogenic sediments from five deep-sea drill cores, that were exposed to maximum temperatures between ~10° and 70°C over geological time scales of ~15–120 Ma. Mean track lengths (MTL) and etch pit diameters (Dpar) of all samples were measured, and the chemical composition of each grain analyzed for age and track length measurements was determined by electron microprobe analysis. Thermal histories of the sampled sites were independently reconstructed, based on vitrinite reflectance measurements and/or 1D numerical modelling. These reconstructions were used to test the most widely used annealing models for their ability to predict low-temperature annealing. Our results show that long-term exposure to temperatures below the temperature range of the nominal apatite fission track partial annealing zone results in track shortening ranging between 4 and 11%. Both chlorine content and Dpar values explain the downhole annealing patterns equally well. Low chlorine apatite from one drill core revealed a systematic relation between Si-content and Dpar value. The question whether Si-substitution in apatite has direct and systematic effects on annealing properties however, cannot be addressed by our data. For samples, which remained at temperatures 30°C, the predictions of the Laslett et al. (1987) model agree with the measured MTL data within error levels. With few exceptions, predictions by the Ketcham et al. [Ketcham R., Donelick R. and Carlson W. (1999) Variability of apatite fission-track annealing kinetics. III: Extrapolation to geological time scales. Am. Mineral. 84/9, 1235–1255] annealing model are consistent with the measured data for samples which remained at temperatures below ~30°C. For samples which experienced maximum temperatures between ~30 and 70°C, and which are rich in chlorine, the Ketcham et al. (1999) model overestimates track annealing.

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Spiegel, Cornelia, Kohn, Barry, Raza, Asaf, Rainer, Thomas, Gleadow, Andrew (2007). Dataset: Age and chemical composition of apatites from five DSDP and ODP Sites in the Pacific, Atlantic and Indian Oceans. https://doi.org/10.1594/PANGAEA.704785

DOI retrieved: 2007

Additional Info

Field Value
Imported on November 30, 2024
Last update November 30, 2024
License CC-BY-3.0
Source https://doi.org/10.1594/PANGAEA.704785
Author Spiegel, Cornelia
Given Name Cornelia
Family Name Spiegel
More Authors
Kohn, Barry
Raza, Asaf
Rainer, Thomas
Gleadow, Andrew
Source Creation 2007
Publication Year 2007
Resource Type application/zip - filename: Spiegel-2007
Subject Areas
Name: Chemistry

Name: Lithosphere

Related Identifiers
Title: The effect of long-term low-temperature exposure on apatite fission track stability: A natural annealing experiment in the deep ocean
Identifier: https://doi.org/10.1016/j.gca.2007.06.060
Type: DOI
Relation: IsSupplementTo
Year: 2007
Source: Geochimica et Cosmochimica Acta
Authors: Spiegel Cornelia , Kohn Barry , Raza Asaf , Rainer Thomas , Gleadow Andrew .