TOC, carbonate, opal composition and trace element concentration from ODP Holes 175-1082A and 175-1084A

Distinctive light-dark color cycles in sediment beneath the Benguela Current Upwelling System indicate repetitive alternations in sediment delivery and deposition. Geochemical proxies for paleoproductivity and for depositional conditions were employed to investigate the paleoceanographic processes involved in creating these cycles in three mid-Pleistocene intervals from ODP Sites 1082 and 1084. Concentrations of total organic carbon (TOC) vary between 3.5 and 17.1%. Concentrations of CaCO3 vary inversely to TOC and Al, which suggests that both carbonate dissolution and terrigenous dilution contribute to the light-dark cycles. Opal concentrations are independent of both TOC and CaCO3, therefore eliminating diatom production and lateral transport of shelf material as causes of the light-dark cycles. d13Corg and d15Ntot values do not vary across light-dark sediment intervals, implying that the extent of relative nutrient utilization did not change. The stable d15Ntot values represent a balanced change in nitrate supply and export production and therefore indicate that productivity was elevated during deposition of the TOC-rich layers. Parallel changes in concentrations of indicator trace elements and TOC imply that changes in organic matter delivery influenced geochemical processes on the seafloor by controlling consumption of pore water oxygen. Cu, Ni, and Zn are enriched in the darker sediment as a consequence of greater organic matter delivery. Redox-sensitive metals vary due to loss (Mn and Ba) or enrichment (Mo) under reducing conditions created by TOC oxidation. Organic matter delivery impacts subsequent geochemical changes such as carbonate dissolution, sulfate reduction and the concentration of metals. Thus, export production is considered ultimately responsible for the generation of the color cycles.

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Robinson, Rebecca S, Meyers, Philip A, Murray, Richard W (2002). Dataset: TOC, carbonate, opal composition and trace element concentration from ODP Holes 175-1082A and 175-1084A. https://doi.org/10.1594/PANGAEA.744049

DOI retrieved: 2002

Additional Info

Field Value
Imported on November 30, 2024
Last update November 30, 2024
License CC-BY-3.0
Source https://doi.org/10.1594/PANGAEA.744049
Author Robinson, Rebecca S
Given Name Rebecca S
Family Name Robinson
More Authors
Meyers, Philip A
Murray, Richard W
Source Creation 2002
Publication Year 2002
Resource Type application/zip - filename: Robinson_2002
Subject Areas
Name: Lithosphere

Name: Oceans

Related Identifiers
Title: Geochemical evidence for variations in delivery and deposition of sediment in Pleistocene light-dark color cycles under the Benguela Current Upwelling System
Identifier: https://doi.org/10.1016/S0025-3227(01)00217-1
Type: DOI
Relation: IsSupplementTo
Year: 2002
Source: Marine Geology
Authors: Robinson Rebecca S , Meyers Philip A , Murray Richard W .